Oil shale is an organic-rich Granularity sedimentary rock containing kerogen (a solid mixture of Organic compound) from which liquid can be produced. In addition to kerogen, general composition of oil shales constitutes inorganic substance and . Based on their deposition environment, oil shales are classified as marine, lacustrine and terrestrial oil shales. Oil shales differ from oil- bearing shales, shale deposits that contain petroleum (tight oil) that is sometimes produced from drilled wells. Examples of oil- bearing shales are the Bakken Formation, Pierre Shale, Niobrara Formation, and Eagle Ford Formation. Accordingly, shale oil produced from oil shale should not be confused with tight oil, which is also frequently called shale oil.
A 2016 estimate of global deposits set the total world resources of oil shale equivalent of of oil in place.WEC (2016), p. 16 Oil shale has gained attention as a potential abundant source of oil. However, the various attempts to develop oil shale deposits have had limited success. Only Estonia and China have well-established oil shale industries, and Brazil, Germany, and Russia utilize oil shale to some extent.Dyni (2010), pp. 103–122
Oil shale can be combustion directly in furnaces as a low-grade fuel for power generation and district heating or used as a raw material in chemical and construction-materials processing. Heating oil shale to a sufficiently high temperature causes the chemical process of pyrolysis to yield a vapor. Upon cooling the vapor, the liquid unconventional oil, called shale oil, is separated from combustible oil-shale gas. Shale oil is a substitute for conventional crude oil; however, extracting shale oil is costlier than the production of conventional crude oil both financially and in terms of its environmental impact. Oil-shale mining and processing raise a number of environmental concerns, such as land use, waste management, Water resources, Water pollution, Greenhouse gas and air pollution.
According to the petrologist Adrian C. Hutton of the University of Wollongong, oil shales are not "geological nor geochemically distinctive rock but rather 'economic' term". Their common defining feature is low solubility in low-boiling organic solvents and generation of liquid organic products on thermal decomposition.
Geologists can classify oil shales on the basis of their composition as carbonate-rich shales, Silicon dioxide shales, or Cannel coal shales.Lee (1990), p. 10Oil shale differs from bitumen-impregnated rocks (other so-called unconventional resources such as oil sands and petroleum reservoir rocks), Humic substance coals and shale. While oil sands do originate from the biodegradation of oil, heat and pressure have not (yet) transformed the kerogen in oil shale into petroleum, which means its maturation does not exceed early mesocatagenetic.
Oil shales differ also from oil-bearing shales, shale deposits that contain tight oil that is sometimes produced from drilled wells. Examples of oil-bearing shales are the Bakken Formation, Pierre Shale, Niobrara Formation, and Eagle Ford Formation. Accordingly, shale oil produced from oil shale should not be confused with tight oil, which is called also frequently shale oil.WEC (2013), p. 2.46IEA (2013), p. 424
composition of oil shales constitutes inorganic matrix, bitumens, and kerogen. While the bitumen portion of oil shales is soluble in carbon disulfide, the kerogen portion is insoluble in carbon disulfide and may contain iron, vanadium, nickel, molybdenum, and uranium.
Oil shale contains a lower percentage of organic matter than coal. In commercial grades of oil shale the ratio of organic matter to mineral matter lies approximately between 0.75:5 and 1.5:5. At the same time, the organic matter in oil shale has an atomic ratio of hydrogen to carbon (H/C) approximately 1.2 to 1.8 times lower than for crude oil and about 1.5 to 3 times higher than for coals.Dyni (2010), p. 94van Krevelen (1993), p. ? The organic components of oil shale derive from a variety of organisms, such as the remains of algae, , pollen, and corky fragments of Herbaceous plant and woody plants, and cellular debris from other aquatic and land plants. Some deposits contain significant ; Germany's Messel pit has the status of a UNESCO World Heritage Site. The mineral matter in oil shale includes various fine-grained Silicon dioxide and carbonates. Inorganic matrix can contain quartz, feldspar, clay (mainly illite and chlorite), carbonate (calcite and dolomite), pyrite and some other minerals.Another classification, known as the van Krevelen diagram, assigns kerogen types, depending on the hydrogen, carbon, and oxygen content of oil shales' original organic matter. The most commonly used classification of oil shales, developed between 1987 and 1991 by Adrian C. Hutton, adapts Petrography terms from coal terminology. This classification designates oil shales as terrestrial, lacustrine (lake-bottom-deposited), or marine (ocean bottom-deposited), based on the environment of the initial biomass deposit. Known oil shales are predominantly of aquatic (marine, lacustrine) origin. Hutton's classification scheme has proven useful in estimating the yield and composition of the extracted oil.Dyni (2010), p. 95
Although resources of oil shale occur in many countries, only 33 countries possess known deposits of potential economic value.
Well-explored deposits, potentially classifiable as reserves, include the Green River deposits in the western United States, the Tertiary deposits in Queensland, Australia, deposits in Sweden and Estonia, the El-Lajjun deposit in Jordan, and deposits in France, Germany, Brazil, China, southern Mongolia and Russia. These deposits have given rise to expectations of yielding at least 40 liters of shale oil per tonne of oil shale, using the Fischer Assay.
A 2016 estimate set the total world resources of oil shale equivalent to yield of of shale oil, with the largest resource deposits in the United States accounting more than 80% of the world total resource. For comparison, at the same time the world's proven oil reserves are estimated to be .WEC (2016), p. 14 The largest deposits in the world occur in the United States in the Green River Formation, which covers portions of Colorado, Utah, and Wyoming; about 70% of this resource lies on land owned or managed by the United States federal government. Deposits in the United States constitute more than 80% of world resources; other significant resource holders being China, Russia, and Brazil. The amount of economically recoverable oil shale is unknown.
Around 3000 BC, "rock oil" was used in Mesopotamia for road construction and making architectural adhesives. Celtic Britons of the Iron Age used tractable oil shales to fashion for burial, or just polish it to create ornaments.
In the 10th century, the Arab physician Masawaih al-Mardini (Mesue the Younger) described a method of extraction of oil from "some kind of bituminous shale".
The first patent for extracting oil from oil shale was British Crown Patent 330 granted in 1694 to Martin Eele, Thomas Hancock and William Portlock, who had "found a way to extract and make great quantities of pitch, tarr, and oyle out of a sort of stone".Mushrush (1995), p. 39Cane (1976), p. 56Modern industrial mining of oil shale began in 1837 in Autun, France, followed by exploitation in Scotland, Germany, and several other countries.Dyni (2010), p. 96 Operations during the 19th century focused on the production of kerosene, lamp oil, and Paraffin wax; these products helped supply the growing demand for lighting that arose during the Industrial Revolution, supplied from Scottish oil shales.
Fuel oil, lubricating oil and grease, and ammonium sulfate were also produced.
Scottish production peaked in around 1913, operating 120 oil shale works, producing 3,332,000 tonnes of oil shale, generating around 2% of the global production of petroleum. The Scottish oil-shale industry expanded immediately before World War I partly because of limited access to conventional petroleum resources and the mass production of automobiles and trucks, which accompanied an increase in gasoline consumption; but mostly because the British Admiralty required a reliable fuel source for their fleet as war in Europe loomed.
Although the Estonian and Chinese oil-shale industries continued to grow after World War II, most other countries abandoned their projects because of high processing costs and the availability of cheaper petroleum.Dyni (2010), p. 97
Following the 1973 oil crisis, world production of oil shale reached a peak of 46 million tonnes in 1980 before falling to about 16 million tonnes in 2000, because of competition from cheap conventional petroleum in the 1980s.
On 2 May 1982, known in some circles as "Black Sunday", ExxonMobil canceled its US$5 billion Colony Shale Oil Project near Parachute, Colorado, because of low oil prices and increased expenses, laying off more than 2,000 workers and leaving a trail of home foreclosures and small business bankruptcies.
In 1986, President Ronald Reagan signed into law the Consolidated Omnibus Budget Reconciliation Act of 1985, which among other things abolished the United States' Synthetic Liquid Fuels Program.
The global oil-shale industry began to revive at the beginning of the 21st century. In 2003, an oil-shale development program restarted in the United States. Authorities introduced a commercial leasing program permitting the extraction of oil shale and oil sands on federal lands in 2005, in accordance with the Energy Policy Act of 2005.
, 80% of oil shale used globally is extracted in Estonia, mainly because Estonia uses several oil-shale-fired power plants,
which has an installed capacity of 2,967 (MW). By comparison, China's oil shale power plants have an installed capacity of 12 MW, and Germany's have 9.9 MW.
A 470 MW oil shale power plant in Jordan is under construction as of 2020. Israel, Romania and Russia have in the past run power plants fired by oil shale but have shut them down or switched to other fuel sources such as natural gas.
Other countries, such as Egypt, have had plans to construct power plants fired by oil shale, while Canada and Turkey had plans to burn oil shale along with coal for power generation.
Oil shale serves as the main fuel for power generation only in Estonia, where 90.3% of country's electrical generation in 2016 was produced from oil shale.
According to the World Energy Council, in 2008 the total production of shale oil from oil shale was 930,000 tonnes, equal to , of which China produced 375,000 tonnes, Estonia 355,000 tonnes, and Brazil 200,000 tonnes.Dyni (2010), pp. 101–102 In comparison, production of the conventional oil and natural gas liquids in 2008 amounted 3.95 billion tonnes or .Dyni (2010), pp. 59–61
The extraction of the useful components of oil shale usually takes place above ground ( ex-situ processing), although several newer technologies perform this underground (on-site or In situ processing). In either case, the chemical process of pyrolysis converts the kerogen in the oil shale to shale oil (synthetic crude oil) and oil shale gas. Most conversion technologies involve heating shale in the absence of oxygen to a temperature at which kerogen decomposes (pyrolyses) into gas, condensable oil, and a solid residue. This usually takes place between and . The process of decomposition begins at relatively low temperatures () but proceeds more rapidly and more completely at higher temperatures.
In-situ processing involves heating the oil shale underground. Such technologies can potentially extract more oil from a given area of land than ex-situ processes, since they can access the material at greater depths than surface mines can. Several companies have patented methods for in-situ . However, most of these methods remain in the experimental phase. Two in-situ processes could be used: true in-situ processing does not involve mining the oil shale, while modified in-situ processing involves removing part of the oil shale and bringing it to the surface for modified in-situ retorting in order to create permeability for gas flow in a rubble chimney. Explosives rubblize the oil-shale deposit.
Hundreds of patents for oil shale retorting technologies exist;
however, only a few dozen have undergone testing. By 2006, only four technologies remained in commercial use: Kiviter process, Galoter process, Fushun process, and Petrosix.
The shale oil derived from oil shale does not directly substitute for crude oil in all applications. It may contain higher concentrations of Alkene, oxygen, and nitrogen than conventional crude oil. Some shale oils may have higher sulfur or arsenic content. By comparison with West Texas Intermediate, the benchmark standard for crude oil in the futures contract market, the Green River shale oil sulfur content ranges from near 0% to 4.9% (in average 0.76%), where West Texas Intermediate's sulfur content has a maximum of 0.42%.
The sulfur content in shale oil from Jordan's oil shales may be as high as 9.5%.
The arsenic content, for example, becomes an issue for Green River formation oil shale. The higher concentrations of these materials means that the oil must undergo considerable upgrading (hydrotreating) before serving as oil refinery feedstock.Lee (1990), p. 6 Above-ground retorting processes tended to yield a lower API gravity shale oil than the in situ processes. Shale oil serves best for producing middle-Distillation such as kerosene, jet fuel, and diesel fuel. Worldwide demand for these middle distillates, particularly for diesel fuels, increased rapidly in the 1990s and 2000s.
However, appropriate refining processes equivalent to hydrocracking can transform shale oil into a lighter-range hydrocarbon (gasoline).
In 2010, the International Energy Agency estimated, based on the various pilot projects, that investment and operating costs would be similar to those of Canadian oil sands, that means would be economic at prices above $60 per barrel at current costs. This figure does not account carbon pricing, which will add additional cost. According to the New Policies Scenario introduced in its World Energy Outlook 2010, a price of $50 per tonne of emitted adds additional $7.50 cost per barrel of shale oil. As of November 2021, the price of tonne of exceeded $60.
A 1972 publication in the journal Pétrole Informations () compared shale-based oil production unfavorably with coal liquefaction. The article portrayed coal liquefaction as less expensive, generating more oil, and creating fewer environmental impacts than extraction from oil shale. It cited a conversion ratio of of oil per one ton of coal, as against of shale oil per one ton of oil shale.
A critical measure of the viability of oil shale as an energy source lies in the ratio of the energy produced by the shale to the energy used in its mining and processing, a ratio known as "energy return on investment" (EROI). A 1984 study estimated the EROI of the various known oil-shale deposits as varying between 0.7–13.3,
although known oil-shale extraction development projects assert an EROI between 3 and 10. According to the World Energy Outlook 2010, the EROI of ex-situ processing is typically 4 to 5 while of in-situ processing it may be even as low as 2. However, according to the IEA most of used energy can be provided by burning the spent shale or oil-shale gas. To increase efficiency when retorting oil shale, researchers have proposed and tested several co-pyrolysis processes.
These include acid drainage induced by the sudden rapid exposure and subsequent oxidation of formerly buried materials; the introduction of metals including mercuryWestern Oil Shale Has a High Mercury Content http://www.westernresearch.org/uploadedFiles/Energy_and_Environmental_Technology/Unconventional_Fuels/Oil_Shale/MercuryinOilShale.pdf into surface-water and groundwater; increased erosion, sulfur-gas emissions; and air pollution caused by the production of particulates during processing, transport, and support activities.
Oil-shale extraction can damage the biological and recreational value of land and the ecosystem in the mining area. Combustion and thermal processing generate waste material. In addition, the atmospheric emissions from oil shale processing and combustion include carbon dioxide, a greenhouse gas. Environmentalists oppose production and usage of oil shale, as it creates even more greenhouse gases than conventional fossil fuels. Experimental in situ conversion processes and carbon capture and storage technologies may reduce some of these concerns in the future, but at the same time they may cause other problems, including groundwater pollution.
Among the water contaminants commonly associated with oil shale processing are oxygen and nitrogen heterocyclic hydrocarbons. Commonly detected examples include quinoline derivatives, pyridine, and various alkyl homologues of pyridine, such as picoline and lutidine.Sims, G. K. and E.J. O'Loughlin. 1989. Degradation of pyridines in the environment. CRC Critical Reviews in Environmental Control. 19(4): 309–340.
Water concerns are sensitive issues in arid regions, such as the western U.S. and Israel's Negev, where plans exist to expand oil-shale extraction despite a water shortage. Depending on technology, above-ground retorting uses between one and five barrels of water per barrel of produced shale-oil.
A 2008 programmatic environmental impact statement issued by the U.S. Bureau of Land Management stated that surface mining and retort operations produce of waste water per of processed oil shale. In situ processing, according to one estimate, uses about one-tenth as much water.
environmentalism activists, including members of Greenpeace, have organized strong protests against the oil shale industry. In one result, Queensland Energy Resources put the proposed Stuart Oil Shale Project in Australia on hold in 2004.
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